Pemanfaatan Ekstrak Lignin Dari Kulit Jengkol (Pithecellobium jiringa) Sebagai Inhibitor Korosi Baja Lunak Dalam Medium HCl

Authors

  • Emriadi Emriadi Universitas Andalas
  • Savira Nurul Hayuni
  • Yeni Stiadi

DOI:

https://doi.org/10.25077/jku.11.2.14-21.2022

Keywords:

Pithecellobium jiringa, lignin, corrosion inhibition, weight loss, adsorption

Abstract

Lignin extract from jengkol peel (Pithecellobium jiringa) as a mild steel corrosion inhibitor in 1 M HCl solution was studied using weight loss method, characterization Fourier Transform Infra Red (FTIR), Ultraviolet-Visible (UV-Vis) spectroscopy, and optical microscopy. The inhibition efficiency increased with increasing temperature and the concentration of lignin extract in 1 M HCl solution. The highest efficiency value was 90,1% with the addition of 10 g/L extracts at 60°C. The adsorption of lignin extract from jengkol peel followed the Langmuir adsorption isotherm. Thermodynamic parameters such as Gibbs energy (ΔG), enthalpy (ΔH), entropy (ΔS), and activation energy were calculated to determine the mechanism of corrosion inhibition. FTIR analysis and UV-Vis spectroscopy showed an interaction between lignin extract from jengkol peel and mild steel surface. Optical microscopy analysis showed that lignin extract from jengkol peel could reduce the formation of rust on the steel surface.

References

L. Anggraini, Emriadi, A. Alif, The extract of siamih (Ageratum conyzoides L) leaf as a green eco-friendly corrosion inhibitor for the mild steel St. 37 in HCl solution, Int. J. Res. Rev. 7 (2020) 480–488.

H. Kumar, V. Yadav, Highly efficient and eco-friendly acid corrosion inhibitor for mild steel: Experimental and theoretical study, J. Mol. Liq. 335 (2021) 116220.

A.R. Shahmoradi, N. Talebibahmanbigloo, A.A. Javidparvar, G. Bahlakeh, B. Ramezanzadeh, Studying the adsorption/inhibition impact of the cellulose and lignin compounds extracted from agricultural waste on the mild steel corrosion in HCl solution, J. Mol. Liq. 304 (2020) 112751.

W. Zhang, Y. Ma, L. Chen, L. Wang, Y. Wu, H. Li, Aloe polysaccharide as an eco-friendly corrosion inhibitor for mild steel in simulated acidic oil field water : Experimental and theoretical approaches, J. Mol. Liq. 307 (2020) 112950.

S. Yahya, N.K. Othman, M.C. Ismail, Corrosion inhibition of steel in multiple flow loop under 3.5% NaCl in the presence of rice straw extracts, lignin and ethylene glycol, Eng. Fail. Anal. 100 (2019) 365–380.

P.P. Rahayu, C.D.D. Sundari, I. Farida, Corrosion inhibition using lignin of sugarcane bagasse, IOP Conf. Ser. Mater. Sci. Eng. 434 (2018) 012087.

K.K. Alaneme, S.J. Olusegun, Corrosion inhibition performance of lignin extract of sun flower (Tithonia Diversifolia) on medium carbon low alloy steel immersed in H2SO4 solution, Leonardo J. Sci. 20 (2012) 59–70.

S. Rozi, Emriadi, Y. Stiadi, Pemanfaatan ekstrak etanol kulit jengkol (Pithecellobium jiringa) sebagai inhibitor korosi baja St.37 dalam medium asam klorida, J. Kim. Unand. 3 (2014) 39–47.

N. Hidayah, R. Lubis, K.G. Wiryawan, S. Suharti, Phenotypic identification, nutrients content, bioactive compounds of two jengkol (Archidendron jiringa) varieties from Bengkulu, Indonesia and their potentials as ruminant feed, Biodiversitas. 20 (2019) 1671–1680.

Y. Stiadi, M. Efdi, H. Aziz, Emriadi, Gleichenia linearis Burm. Leaf extract as corrosion inhibitor of mild steel in hydrochloric acid medium, Int. J. Corros. Scale Inhib. 9 (2020) 1498–1515.

N. Hossain, M.A. Chowdhury, A.K.M.P. Iqbal, M.S. Islam, N.Y. Sheikh Omar, A.Z.A. Saifullah, Paederia Foetida leaves extract as a green corrosion inhibitor for mild steel in hydrochloric acid solution, Curr. Res. Green Sustain. Chem. 4 (2021) 100191.

Emriadi, P. Untari, M. Efdi, Leave extract of Syzygium malaccenseas green inhibitor of mild steel in acidic medium, Rasayan J. Chem. 14 (2021) 569–577.

H. Khoshsang, A. Ghaffarinejad, Sunflower petals extract as a green, eco-friendly and effective corrosion bioinhibitor for carbon steel in 1M HCl solution, Chem. Data Collect. 37 (2022) 100799.

M.H. Hussin, A. Abdul, M. Nasir, M. Ibrahim, N. Brosse, The capability of ultrafiltrated alkaline and organosolv oil palm (Elaeis guineensis)

Downloads

Published

2022-11-30

How to Cite

Emriadi, E., Savira Nurul Hayuni, & Yeni Stiadi. (2022). Pemanfaatan Ekstrak Lignin Dari Kulit Jengkol (Pithecellobium jiringa) Sebagai Inhibitor Korosi Baja Lunak Dalam Medium HCl. Jurnal Kimia Unand, 11(2), 14–21. https://doi.org/10.25077/jku.11.2.14-21.2022

Issue

Vol. 11 No. 2 (2022): November 2022

Section

Articles

License

Copyright (c) 2023 Jurnal Kimia Unand

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Please find the rights and licenses in Jurnal Kimia Unand (J. Kim. Unand).  Authors who publish with J. Kim. Unand agree to the following policies. No specific document sign-off is required.

1. License

The use of the article will be governed by the Creative Commons Attribution license as currently displayed on Creative Commons Attribution 4.0 International License.Â

2. Author(s)' Warranties

The author warrants that the article is original, written by the stated author(s), has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author(s).

3. User Rights

Under the Creative Commons license, the journal permits users to copy, distribute, and display the material. Users will also need to attribute authors and J. Kim. Unand on distributing works in the journal and other media of publications.

4. Rights of Authors

Authors retain all their rights to the published works, such as (but not limited to) the following rights;

  • Copyright and other proprietary rights relating to the article, such as patent rights,
  • The right to use the substance of the article in own future works, including lectures and books,
  • The right to reproduce the article for own purposes,
  • The right to self-archive the article,
  • The right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the article's published version (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.

5. Co-Authorship

Suppose more than one author jointly prepared the article. In that case, any author submitting the manuscript warrants that he/she has been authorized by all co-authors to be agreed on this copyright and license notice (agreement) on their behalf; and agrees to inform his/her co-authors of the terms of this policy. J. Kim. Unand will not be held liable for anything arising due to the author(s) internal dispute. J. Kim. Unand will only communicate with the corresponding author.

6. Royalties

By submitting the articles, the authors agreed that no fees are payable from J. Kim. Unand.

7. Privacy Statement 

The names and email addresses entered in this journal site will be used exclusively for the stated purposes of this journal and will not be made available for any other purpose or to any other party.

However, due to the advancement and availability of hacking and data mining techniques found over the Internet,  J. Kim. Unand cannot guarantee that other parties will not mine our users' email addresses in any possible ways found over the Internet.

8. Miscellaneous

J. Kim. Unand will publish the article (or have it published) in the journal if the article’s editorial process is completed and J. Kim. Unand has become obligated to have the article published. The author acknowledges that the article may be published so that it will be publicly accessible, and such access will be free of charge for the readers.